Welcome to the Community!!
You can invite multiple users via differenet methods
Create a Group, add the users to group and then add the respective group to the repository with neccessary permission, if the permissions are different for users, you will have to create different groups in that case
Another way is to add the user's via API to the repository
Here's the guide on the same
https://community.atlassian.com/t5/Bitbucket-articles/Bitbucket-API-s/ba-p/2090249#M1850
Let me know if you have any queries
Thanks,
Pramodh
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