Thanks for including so many details. It looks like you are sizing your tables in the Source Editor, which can introduce user errors, but it looks fine.
I found a good workaround in this ticket: Each column has same width in a table regardless of the contents on exported PDF It's not the exact same issue but the PDF stylesheet suggested did improve my export. What I did was go to Space Tools>Look and Feel and add the following to the PDF stylesheet:
Here is my Confluence page:
Without the PDF stylesheet my export looked like:
After I added the stylesheet:
A little background: PDF exports of tables have been historically problematic - check out this partial list of bugs:
I look forward to hearing whether a PDF stylesheet helps you get the exports the way you want them.
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