You can watch this video tutorial for beginners and power-users https://www.youtube.com/playlist?list=PLRpx9wuFqlzHWzFNthGvASXGzEKAjXYGb
and continue with this advanced course for Confluence administrators https://www.youtube.com/playlist?list=PLRpx9wuFqlzFokAJdzlLM-1t7SMiwcO96
This contains what you need to start with Confluence. I would recommend the Get Started guide, this guides you through the basics of administration.
Furthermore, it completely depends on what you want to achieve, do you want to work with restrictions, spaces, macros, or something else?
I assume you got Confluence for a reason, maybe it's good to explain what you want to achieve, so we can help you :-). Good luck!
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