Thanks for contacting with Opsgenie. Since Quiet Hours shows the time-frame that you do not want to be notified, they can be disabled manually for taking notifications while you are on-call.
Feel free to reach us, if you will have further questions :)
Thank you for contacting Opsgenie Community!
Basically, Quiet Hours allows you to define a scheduled time period when you don't want to receive notifications. Therefore, they need to be enabled manually when you are on-call.
Hope my answer was helpful,
Let us know if anything else is needed, would be more than happy to help!
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