The concern in Custom Field is, even you add checkbox as for approval, say NameA, NameB, NameC etc., any one of A/B/C could mistakenly click the wrong checkbox; in Approvals, the account owner only can check and approve under his/her name since other name checkbox was blanked already.
So back to top of my question, still looking for a way to automation the card when someone brings into "Submitted for Approval" list, Trello would automatically give "For Approval" Label, re-setup due to 4 hrs later, and give the default name as approval name on card.
An another possible way
Add a checklist titled Approvals to the parentcard.
Each item of this checklist corresponds to an approver.
Create a board for each approver.
Convert all the items into linked cards.
Dispatch each linked card in appropriate board
(for this use pattern, wildcard & appropriate name,
When a card is done in the personal board, check the item in the checklist approvals.
When the checklist is complete, move the parentcard to "approved" list.
If you had to thrive a new habit during a lockdown, what would it be? Trello
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