I am going to answer your questions inline:
1) How to migrate Test cases from QC to Zephyr
Zephyr - Are you able to export out of QC to an excel format? If so, what you will do is export the test cases from QC to an excel sheet. Once in excel sheet format you can import them into Zephyr. You will need to use the Zephyr for JIRA tests utility inporter in order to import into Zephyr for JIRA. You can access the import and its documentation at the following link:
2) Is it possible to execute Manual and Automation scripts(QTP,Selenium etc.,) from within Zephyr and if not, anyother add-in ...
Zephyr - Yes. You will want to use ZAPI. ZAPI is our Zephyr for JIRA API's that allow you to bring automation into Zephyr for JIRA. Below is some information to help you get started using ZAPI:
A video to help get you started:
Our ZAPI REST API library:
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