I've used both of their remote APIs to poke data into them from discovery systems (SOAP at the time, but newer versions have REST instead), but it was nothing particularly complex or clever and was all done with custom scripts in the client applications.
If you're thinking of network discovery of assets, I would now have a look at Mindville's Insight with the accompanying discovery - https://marketplace.atlassian.com/apps/1214668/insight-discovery?hosting=datacenter&tab=overview
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