The best way to do this is to export the users to .CSV format and then import the .CSV data into the LDAP directory. You can export your JIRA data to .CSV by using the SQL cripts on the linked page, but you will need to check your user manual for how to import the .CSV into your LDAP dircetory: https://confluence.atlassian.com/display/JIRA/How+to+Export+Users+to+CSV+from+JIRA
All the best,
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