Yes. Look at the "notfication scheme" for the project, you've got a wide range of options on who you can send email to.
Hi Leary, every transition in a workflow has the posibility to add an event in the post-function. There you can use the Issue created event. Remember to configure your notification scheme.
https://confluence.atlassian.com/display/JIRA052/Configuring+Email+Notifications
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