Are you talking about workflow schemes?
As far as I know, it is currently not possible to configure a a custom workflow to be the default workflow. However, I did find an improvement request for this here - https://jira.atlassian.com/browse/JRA-9363.
For now, I would recommend that you :
* Vote, so that it will receive more attention
* Watch it, so that you will receive any and all updates
* Comment, and give your opinion on the matter
Please note that the implementation of new features and improvement requests falls under https://confluence.atlassian.com/display/DEV/Implementation+of+New+Features+Policy.
Out of the box - it's not possible today. There are a couple of add ons on the Atlassian Marketplace that does this though, including ours: https://marketplace.atlassian.com/plugins/com.wittified.jira.project-creator .
One of the benefits of the Project Creator for JIRA add-on is that it allows you to delegate to non-administrators to create projects (from the templates) as well.
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