Have a look at https://JIRA-URL/plugins/servlet/applications/versions-licenses and let me know what you see there. For me, I had installed Jira Software but I didn't activate the separate license yet (it's an additional license to the regular Jira one:
Once I clicked to try it for free (or you can buy it now) I was able to have Jira Software activated.
So if you can show us what you see from that page it will help us to get Jira Software activated on your instance.
You will want to raise another question for your issues with DVCS connector as it is not related to this Jira Software licensing issue.
...PermissionsStartOnly=true User=www-data Group=www-data ExecStart=/opt/jira/bin/startup.sh ExecStop=/opt/jira/bin/shutdown.sh TimeoutStartSec=120 TimeoutStopSec=600 PrivateTmp=true [Install] WantedBy...
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