Well, "available" is a bit debatable, as the code determines some of the logic around permissions. And what you can and/or should do with permissions is quite a long discussion too.
But the coder's technical answer is: https://docs.atlassian.com/jira/latest/com/atlassian/jira/webtests/Permissions.html - that's the list for 6.4, it should be updated for 7 soon.
I have multiple projects that use variations of the same base workflow. The variations depend on the requirements of the project or issue type. The variations mostly come in the form of new statuses ...
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