There's no simple way to achieve this, particularly not so specifically. There's no way to extend that menu section with an action outside of defining your own add-on.
What does "as a parameter in URL" mean?
here when we click on this button it should pass all test cases as query string to another site.
can we add button at anywhere in this page?
is it possible using JIRA add-ons to add this button ?
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Steven has already answered that - you need to write an add-on to inject the option.
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