I have created new account by added it manually and tick on the box 'Email a link to user to set their password'. Unfortunetely, the new users seem not received the link on their email.
Do you know what is exactly the reason why they didnt get the invitation mail?
Is your email server configured? If not, take a look at this doc.
If you already have an email server configured, take a look at this document to troubleshoot.
If you are using OnDemand instance, you can also raise a support ticket at https://support.atlassian.com
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