Hi Steve,
As far as I know, this is not possible to choose the users to notify when you post a question. They must watch an specific topics in questions to receive emails. This is better explained here:
https://confluence.atlassian.com/display/AOD/Topics
The best in this case is to open a feature request in jira.atlassian.com for this feature. I couldn't find any request for this feature yet.
I hope this helps.
Cheers,
Rodrigo
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